Inés Zorreguieta, 33, was found dead at her apartment in Buenos Aires late on Wednesday night.
A spokesman for the Dutch Embassy in Argentina told La Nacion that authorities 'assume it was a case of suicide.'
Inés is thought to have suffered from depression and mental health issues.
Her body was removed from her home in the early of hours of Thursday morning and a post-mortem examination will take place.
She was a psychologist who worked for an office on social policies at the president's office.
Inés was also godmother to Queen Maxima's 11-year-old daughter Princess Ariane.
Queen Maxima, 47, has cancelled all upcoming engagements and is set to fly to her native Argentina in the coming hours.
She had been due to attend Holland Festival this week, but her appearance has been cancelled, according to Hello! magazine.
She had also been set to accompany her husband, King Willem-Alexander, on their tour of Estonia, Lithuania and Latvia next week.
Mailonline
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